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The interaction of light with matter at surfaces of dielectrics strongly depends on polarization. Here, we present the first infrared spectroscopic evidence for significant polarization effects in the spectroscopic detection of adsorbate vibrational frequencies. In addition to much larger peak intensities for p-polarized light relative to s-polarization, a small but distinct blue shift was identified for CO adsorbed at the surfaces of two prototype dielectric substrates, CeO2(111) and CaCO3(10.4). A simulation using a layer model yields very good agreement with experiment.
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d Institute of Physical Chemistry, and Abbe Center of Photonics, Friedrich Schiller University, Helmholtzweg 4, Jena D-07743, Germany
a Beijing Key Laboratory of Bio-inspired Energy Materials and Devices, School of Space and Environment, Beihang University, Beijing, China
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Condenser: The purpose of the condenser lens is to focus the light onto the specimen. Microscope condenser lenses are most useful at 400x and higher ...
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c Leibniz Institute of Photonic Technology (IPHT), Albert-Einstein-Str. 9, D-07745 Jena, Germany E-mail: thomas.mayerhoefer@uni-jena.de
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C. Yang, W. Wang, A. Nefedov, Y. Wang, T. G. Mayerhöfer and C. Wöll, Phys. Chem. Chem. Phys., 2020, 22, 17129 DOI: 10.1039/D0CP02399J
Polarity
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The compound microscope has two systems of lenses for greater magnification, 1) the ocular, or eyepiece lens that one looks into and 2) the objective lens, or ...
May 3, 2023 — Types of Polarization: There are three main types of polarization namely, linear polarization, circular polarization, and elliptical ...
b Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany E-mail: christof.woell@kit.edu
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