5.4 A person must load and secure dangerous goods in a means of containment and must load and secure the means of containment on a means of transport in such a way as to prevent, under normal conditions of transport, damage to the means of containment or to the means of transport that could lead to a release of the dangerous goods.

Dangerous goodsSegregation Chartuk

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Dangerous goods loadingchartfor air FedEx

The letter “S” indicates that dangerous may not be loaded, transported, or stored together in the same transport vehicle during the course of transportation unless they are separated in a manner so the dangerous goods will not come into contact with one another in case of an incident where the packages will be leaking. NOTE: Even if separation methods are used, Class 8 (corrosive) liquids may not be loaded above or adjacent to Class 4 (flammable) or Class 5 (oxidizing) materials. However, this requirement does not apply to Class 4 and Class 5 dangerous goods that, when in contact, are known NOT to cause a fire or a dangerous evolution of heat or gas.

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Note: The compatibility letter for the dangerous good "UN0029 DETONATORS, NON-ELECTRIC for blasting" is next to the TDG Class (see Column 3  in Schedule 1). The letter "B" next to "1.1" is the compatibility letter.

This course is updated to meet Transport Canada's educational requirements under the TDG Act and Regulations, for all persons who handle, offer for transport, or transport dangerous goods by road. This course includes the SOR/2020-23 TDG regulatory amendment.

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NOTE: Some incompatible dangerous goods may be allowed to be transported together when their quantity is below a specific threshold limit or when limited quantity packaging is used. A threshold limit can be established by a safety engineer and in consultation with the TDG Directorate.

(***) Class 9 dangerous goods have varied properties, and thus, it is best to check the SDS regarding hazards and get advice from the supplier.

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IATADG segregation chart

Although Canada has not issued a compatibility or segregation chart, a number of different international jurisdictions have compiled such charts in their dangerous goods or hazardous material transport regulations. Caution must be used when following these charts as they are based on the dangerous good’s TDG class. Accurate compatibility charts are those that are based on the chemical properties of the dangerous goods.

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Canada’s TDG Regulations do not include a compatibility table for dangerous goods (the Regulations do include a compatibility table for consignments that consist of explosives only).

DGcompatibilitychart

For example: the assigned compatibility group for UN0004 in Schedule 1 is 1.1D. This explosive can be transported together with other explosives that have the following assigned compatibility letter/group: C, D, E, N, S.   NOTE: If an explosive (e.g., UN0074) is assigned to the compatibility group “A”, then such an explosive cannot be transported with any other explosive.

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(2) Do NOT transport dangerous goods together with food, feeds or other edible materials on the same means of transport (e.g., vehicle).

Chemicalsegregation Chart

The carrier should have a safe operating procedure (SOP) for “load planning” which includes segregation of consignments when multiple consignments will be collected en route. Meanwhile, if a consignor is preparing packages with multiple dangerous goods (e.g., consolidation bins or overpacks), then the consignor’s SOP must include instructions on how to manage the packaging of incompatible dangerous goods.

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This updated course provides an overview of the Transportation of Dangerous Goods (TDG) Act and Regulations. It reflects the most recent regulatory amendments in (SOR/2023-155) and (SOR/2023-206) published in the Canada Gazette, and other significant content updates.

A means of containment (MOC) should be segregated according to the carrier’s loading plan. The carrier’s TDG specialist should determine the incompatibility between the dangerous goods that are intended to be transported. As different consignments are loaded, the loader or driver should follow the safe operating procedure (SOP). The SOP should include information on how to carry out a  segregation check:

Yes. There are a number of commercial software applications available for loading that take into account the compatibility of dangerous goods. These applications are mode (e.g., air, marine, road) and jurisdiction-specific (e.g., Canada, USA). Thus, when deciding to use an application, the software application needs to be selected carefully.

IATADG segregation chart2024

Note: The information below is provided as guidance only. Always check with Transport Canada and the TDG Act and Regulations to ensure compliance.

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Imdgsegregation chart

Table 1: Sample segregation and separation chart for road transportation of dangerous goods (1,2,3)NOTE:  The following table is provided as informational only.  It is not an interpretation of the TDG Act or regulations. Always consult with TDG professionals and reliable chemical information sources when making your determination regarding compatibility.

Except for specific requirements about the loading of explosives, the TDG Regulations do NOT directly address the transportation of incompatible dangerous goods. However, Section 5.4 in Part 5 of the TDG Regulation states:

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(3) Unless able to separate properly, do NOT transport Class 4.3 dangerous goods with any aqueous (water-containing) solutions together.

Segregation does not necessarily refer to keeping dangerous good package A away from dangerous good package B, such as the opposite side of a truck trailer. An accident with A may cause a release of B, or a reaction from one might affect the other.

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Explosives are assigned a compatibility group. See Column 3 in Schedule 1. The compatibility groups are described in Appendix 2 of Part 2 in the TDG Regulations. The Table from Section 5.7 in Part 5 of the TDG Regulation lists the explosives compatibility groups that can be transported together. It is reproduced below with some minor modifications of the column titles.

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When transporting dangerous goods, there is always a risk of spills. If incompatible substances mix because the packages get damaged in an incident, a chemical reaction may produce enough heat to cause fire or explosion or possibly release dangerous gases. For example, chlorine gas is released when a spill of sodium hypochlorite solution comes into contact with a sulphuric acid spill. Chlorine gas is classified with the following TDG class and subsidiary classes in Schedule I of the TDG Regulations: 2.3 (5.1) (8). Thus, chlorine gas is dangerous because it is toxic, can oxidize other materials, and is corrosive.

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Only dangerous goods that are unstable decompose violently or could react dangerously will need to be segregated. Generally, dangerous goods that are unstable are not allowed to be transported in a mixed load or in the same package.

Dangerous goodssegregation chartPDF

Segregation applies to the means of containment (MOC), package, an overpack,  and the means of transport (MOT). The general guidance for dangerous goods that are allowed to be shipped (i.e., they are not forbidden) includes the following:

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The term segregation is used to mean “to put apart from the rest,” “isolate,” or “physically separate from the rest.” Dangerous goods might need to be segregated when:

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Ideally compatibility charts for loading plans are created by using multiple sources, such as the reactivity section in the dangerous good’s Safety Data Sheet (SDS), chemical reference books on reactivity, and consultation with the supplier or shipper. For example, both hydrochloric acid (UN1789) and sodium hydroxide (UN1823 for solids and UN1824 for solutions) are dangerous goods with an assigned TDG  Class 8 in Schedule 1 of the TDG Regulations. Although hydrochloric acid and sodium hydroxide are assigned to the same TDG  class, they are NOT compatible. If these two dangerous goods come into contact with one another, there will be a generation of considerable heat, which could result in the creation or sputtering of corrosive vapours and mists.