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A Class IIIA combustible liquid is any liquid with a closed-cup flash point at or above 140°F (60°C) and below 200°F (93°C).

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The next upcoming article in this topic is all about flammable liquid storage rules for small quantities, and if you are thinking on a larger scale – we will lay out all of the rules and regulations for a hazardous materials warehouse that is coded and approved for flammable liquids.

Perhaps the biggest takeaway from this article is that communication is key in any industry that deals with flammable liquids.

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*When a Category 3 liquid with a flash point at or above 100°F (37.8°C) is heated for use to within 30°F (16.7°C) of its flash point, it shall be handled in accordance with the requirements for a Category 3 liquid with a flash point below 100°F (37.8°C).

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*When a Category 4 flammable liquid is heated for use to within 30°F (16.7°C) of its flash point, it shall be handled in accordance with the requirements for a Category 3 liquid with a flash point at or above 100°F (37.8°C). When liquid with a flash point greater than 199.4°F (93°C) is heated for use to within 30°F (16.7°C) of its flash point, it shall be handled in accordance with the requirements for a Category 4 flammable liquid.

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This will be most obvious in OSHA’s CFR29 1910.106 and CFR29 1926.152 where the regulations for flammable liquid handling and storage exist.

A Class IA flammable liquid is any liquid with a closed-cup flash point below 73°F (23°C) AND with a boiling point below 100°F (38°C).

Keep in mind that the LOWER the flash point the MORE HAZARDOUS a substance is because it is flammable at a lower temperature. So Class IA is the most volatile.

And to make it even EXTRA clear – we created this chart that combines both flammable liquid fire code classes and OSHA categories.

Make sure that you clearly identify which class or category you are referring to – maybe even specify fire code or OSHA. The clearer communication, the safer everyone will be.

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Here is a chart for all of you visual learners that explains the different NFPA flammable liquid classes. Download Chart.

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A Class IB flammable liquid is any liquid with a closed-cup flash point below 73°F (23°C) AND with a boiling point at or above 100°F (38°C).

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Not only are there complicated classifications for flammable liquids, but it also gets even more convoluted on how you are supposed to handle and store each class or category of flammable liquids.

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Flammable liquid categories are specified by the Occupational Safety and Health Administration (OSHA). There are four categories also based on a liquid’s closed-cup flash point and boiling point: Category 1, 2, 3, & 4.

A Category 2 flammable liquid is any liquid with a closed-cup flash point below 73.4°F (23°C) AND with a boiling point above 95°F (35°C).

A Category 1 flammable liquid is any liquid with a closed-cup flash point below 73.4°F (23°C) AND with a boiling point below 95°F (35°C).

As you have seen, fire codes are communicated as flammable liquid class IA, IB, IC, II, IIIA, & IIIB; whereas the U.S. Labor Law is communicated as flammable liquid category 1, 2, 3 & 4.

Pay attention to which laws you need to adhere to in each situation and make sure you are referencing the correct class or category.

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Flammable liquid classes are designated by the National Fire Protection Agency (NFPA) and there are six classes total based on a liquid’s closed-cup flash point and boiling point: Class IA, Class IB, Class IC, Class II, Class IIIA, and Class IIIB.

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