Linearand nonlinear distortion

a Department of Chemistry, University of Durham, South Road, Durham, UK E-mail: jon.steed@durham.ac.uk Fax: +44 (0)191 384 4737 Tel: +44 (0)191 334 2085

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Linear distortionexamples

D. R. Turner, M. B. Hursthouse, M. E. Light and J. W. Steed, Chem. Commun., 2004, 1354 DOI: 10.1039/B402884H

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Nonlinear distortion

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A series of compounds of the type [M(1)4(H2O)2]SO4·2H2O containing a simple urea-based pyridyl ligand have been synthesised and characterised by X-ray crystallography. The enclathrated water exists within discrete linearly stacked cavities and causes significant distortions in the M–OH2 bonds due to the presence of a strongly hydrogen bonded water square.

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