The larger the time delay between the two pulses, the more molecules have already decayed. This increase in fragments ultimately allows researchers to determine the duration of the process and the respective rates for the two decay channels.

Extreme ultravioletlithography machine

You can now return your online order in a few easy steps. Select your preferred tracked returns service. We have print at home, paperless and collection options available.

*By submitting your email address, you agree to receive marketing emails from nilos.com. Click here to read our privacy policy & terms and conditions

Extreme ultravioletlithography companies

Your email address is used only to let the recipient know who sent the email. Neither your address nor the recipient's address will be used for any other purpose. The information you enter will appear in your e-mail message and is not retained by Phys.org in any form.

Use this form if you have come across a typo, inaccuracy or would like to send an edit request for the content on this page. For general inquiries, please use our contact form. For general feedback, use the public comments section below (please adhere to guidelines).

We keep our content available to everyone. Consider supporting Science X's mission by getting a premium account.

Get weekly and/or daily updates delivered to your inbox. You can unsubscribe at any time and we'll never share your details to third parties.

Ultraviolet lightwavelength

Discover the latest in science, tech, and space with over 100,000 subscribers who rely on Phys.org for daily insights. Sign up for our free newsletter and get updates on breakthroughs, innovations, and research that matter—daily or weekly.

Ultraviolet lightexamples

The decisive factor here is that the spectra of the two laser pulses are very different. "The HHG pulses have a very broad spectrum, which means they consist of light with many different frequencies—in the visible range this could be understood as different colors. The FEL pulses, on the other hand, are much more limited spectrally," explains Ph.D. student and first author of the study Alexander Magunia.

To achieve this, on the one hand, laser pulses are generated with the process of high harmonic generation (HHG), in which infrared light is guided through a gas cell and thereby converted into XUV radiation—known, for example, from this year's Nobel Prize in Physics. On the other hand, a free-electron laser (FEL) is used, in which accelerated electrons emit XUV light. Both methods generate XUV pulses with a duration of femtoseconds, a millionth of a billionth of a second.

Ultraviolet lightfrequency

While the individual atoms in a molecule are held together by their outermost electrons in a kind of negatively charged cloud—they act as a sort of "chemical glue"—inner shell electrons are bound closer to an atomic nucleus and are therefore more localized in the molecule. It is precisely these electrons that can now be specifically excited with XUV radiation. This enables new chemical reaction processes that do not occur naturally on the Earth's surface.

A collaboration of researchers under the lead of the group of PD Dr. Christian Ott in the Department of Prof. Pfeifer at the Max-Planck-Institut für Kernphysik in Heidelberg, Germany, has now succeeded in combining two different XUV light sources for the first time, in order to temporally resolve a quantum mechanical dissociation mechanism in oxygen molecules.

ExtremeUV wavelength

This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility:

More information: Alexander Magunia et al, Time-resolving state-specific molecular dissociation with XUV broadband absorption spectroscopy, Science Advances (2023). DOI: 10.1126/sciadv.adk1482 Journal information: Science Advances

Extreme ultravioletlithography

By adding the second HHG pulse with an adjustable time delay to the first exciting FEL pulse, this molecular dissociation can now be recorded experimentally—like in a fast photo series. The HHG pulses make it possible to "photograph" all the resulting fragments at once through their spectral absorption fingerprints—a decisive step.

For the first time, researchers have succeeded in selectively exciting a molecule using a combination of two extreme-ultraviolet light sources and causing the molecule to dissociate while tracking it over time. This is another step towards specific quantum mechanical control of chemical reactions, which could enable new, previously unknown reaction channels.

Deepultravioletlithography

The possibility of initiating targeted electronic or molecular processes with FEL pulses and independently reading out a wide range of quantum-mechanical state information about the molecule or its individual fragments with the broadband HHG spectra will hopefully make it possible to record, understand and ultimately control more complex chemical reactions with light in the future.

The interaction of light with matter, especially with molecules, plays an important role in many areas of nature, for example in biological processes such as photosynthesis. Technologies such as solar cells use this process as well.

Our extended Christmas returns policy runs from 28th October until 5th January 2025, all items purchased online during this time can be returned for a full refund.

Store Delivery $6.99 Find out more

On the Earth's surface, mainly light in the visible, ultraviolet or infrared regime plays a role here. Extreme-ultraviolet (XUV) light—radiation with significantly more energy than visible light—is absorbed by the atmosphere and therefore does not reach the Earth's surface. However, this XUV radiation can be produced and used in the laboratory to enable a selective excitation of electrons in molecules.

Standard Delivery $6.99 Find out more

The FEL pulses are generated at the free-electron laser in Hamburg (FLASH@DESY) and used to excite the electrons of the oxygen molecule into a specific state. It is known that this state then causes the molecule to dissociate via two different channels. However, it has been unclear until now how fast this happens. This is because the atoms in the oxygen molecule have to go through a "quantum tunneling" process, which makes exact theoretical descriptions more difficult.