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HandlingPrecautions for safe handlingKeep container tightly sealed.Store in cool, dry place in tightly closed containers.Ensure good ventilation at the workplace.Information about protection against explosions and fires: The product is not flammableConditions for safe storage, including any incompatibilitiesRequirements to be met by storerooms and receptacles: No special requirements.Information about storage in one common storage facility: Store away from oxidizing agents.Further information about storage conditions:Keep container tightly sealed.Store in cool, dry conditions in well-sealed containers.Specific end use(s) No data available
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
Potentiometric chip-based multipumping flow system for the simultaneous determination of fluoride, chloride, pH, and redox potential in water samples.
Fully Rollable Lead-Free Poly(vinylidene fluoride)-Niobate-Based Nanogenerator with Ultra-Flexible Nano-Network Electrodes.
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Tunable Dielectric Properties of Poly(vinylidenefluoride-co-hexafluoropropylene) Films with Embedded Fluorinated Barium Strontium Titanate Nanoparticles.
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Signal word DangerHazard statementsH301 Toxic if swallowed.H315 Causes skin irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.Precautionary statementsP261 Avoid breathing dust/fume/gas/mist/vapors/spray.P280 Wear protective gloves/protective clothing/eye protection/face protection.P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctorP305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P405 Store locked up.P501 Dispose of contents/container in accordance with local/regional/national/international regulations.WHMIS classificationD1A - Very toxic material causing immediate and serious toxic effectsD2B - Toxic material causing other toxic effectsClassification systemHMIS ratings (scale 0-4)(Hazardous Materials Identification System)HEALTHFIREREACTIVITY20 1Health (acute effects) = 2Flammability = 0Physical Hazard = 1Other hazardsResults of PBT and vPvB assessmentPBT: N/AvPvB: N/A
Additional information about design of technical systems:Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.Control parametersComponents with limit values that require monitoring at the workplace:7789-24-4 Lithium fluoride (100.0%)PEL (USA) Long-term value: 2.5 mg/m3as FREL (USA) Long-term value: 2.5 mg/m3as FTLV (USA) Long-term value: 2.5 mg/m3as F, BEIEL (Canada) Long-term value: 2.5 mg/m3as FIngredients with biological limit values:7789-24-4 Lithium fluoride (100.0%)BEI (USA) 2 mg/LMedium: urineTime: prior to shiftParameter: Fluoride (background, nonspecific)3 mg/LMedium: urineTime: end of shiftParameter: Fluoride (background, nonspecific)Additional information: No dataExposure controlsPersonal protective equipmentFollow typical protective and hygienic practices for handling chemicals.Keep away from foodstuffs, beverages and feed.Remove all soiled and contaminated clothing immediately.Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin.Maintain an ergonomically appropriate working environment.Breathing equipment: Use suitable respirator when high concentrations are present.Protection of hands:Impervious glovesInspect gloves prior to use.The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.Penetration time of glove material (in minutes) No data availableEye protection: Safety glassesBody protection: Protective work clothing.
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Information on toxicological effectsAcute toxicity:Toxic if swallowed.The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.LD/LC50 values that are relevant for classification:Oral LD50 143 mg/kg (rat)Skin irritation or corrosion: Causes skin irritation.Eye irritation or corrosion: Causes serious eye irritation.Sensitization: No sensitizing effects known.Germ cell mutagenicity: No effects known.Carcinogenicity:ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.Reproductive toxicity: No effects known.Specific target organ system toxicity - repeated exposure: No effects known.Specific target organ system toxicity - single exposure: May cause respiratory irritation.Aspiration hazard: No effects known.Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
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Extinguishing mediaSuitable extinguishing agents Product is not flammable. Use fire-fighting measures that suit the surrounding fire.Special hazards arising from the substance or mixtureIf this product is involved in a fire, the following can be released:Hydrogen fluoride (HF)Lithium oxideAdvice for firefightersProtective equipment:Wear self-contained respirator.Wear fully protective impervious suit.
See more Lithium products. Lithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek wordlithose which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Compared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics.
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Li7(TeO3)3F: A Lithium Fluoride Tellurite with Large Second Harmonic Generation Responses and a Short Ultraviolet Cutoff Edge.
Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.
Upconversion color tuning in Ce(3+)-doped LiYF4:Yb(3+)/Ho(3+)@LiYF4 nanoparticles towards ratiometric fluorescence detection of chromium(III).
Information on basic physical and chemical propertiesAppearance:Form: Various forms (powder/flake/crystalline/beads, etc.)Color: WhiteOdor: OdorlessOdor threshold: No data available.pH: N/AMelting point/Melting range: 845 °C (1553 °F)Boiling point/Boiling range: 1680 °C (3056 °F)Sublimation temperature / start: No data availableFlammability (solid, gas) No data available.Ignition temperature: No data availableDecomposition temperature: No data availableAutoignition: No data available.Danger of explosion: No data available.Explosion limits:Lower: No data availableUpper: No data availableVapor pressure: N/ADensity at 20 °C (68 °F): 2.635 g/cm3 (21.989 lbs/gal)Relative density No data available.Vapor density N/AEvaporation rate N/ASolubility in / Miscibility withWater at 20 °C (68 °F): 1.3 g/lPartition coefficient (n-octanol/water): No data available.Viscosity:Dynamic: N/AKinematic: N/AOther information No data available
Atypical Hemangioma Mimicking Metastasis on 18F-Sodium Fluoride Positron Emission Tomography-Computed Tomography and Magnetic Resonance Imaging: Gallium-68-Prostate-Specific Membrane Antigen Positron Emission Tomography Improves the Specificity of Bone Le
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Blend-electrospun graphene oxide/Poly(vinylidene fluoride) nanofibrous membranes with high flux, tetracycline removal and anti-fouling properties.
UN-NumberDOT, IMDG, IATA UN3288UN proper shipping nameDOT Toxic solid, inorganic, n.o.s. (Lithium fluoride)IMDG, IATA TOXIC SOLID, INORGANIC, N.O.S. (Lithium fluoride)Transport hazard class(es)DOTClass 6.1 Toxic substances.Label 6.1Class 6.1 (T5) Toxic substancesLabel 6.1IMDG, IATAClass 6.1 Toxic substances.Label 6.1Packing groupDOT, IMDG, IATA IIIEnvironmental hazards: N/ASpecial precautions for user Warning: Toxic substancesTransport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/ATransport/Additional information:DOTMarine Pollutant (DOT): NoUN "Model Regulation": UN3288, Toxic solid, inorganic, n.o.s. (Lithium fluoride), 6.1, III
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Waste treatment methodsRecommendation Consult official regulations to ensure proper disposal.Uncleaned packagings:Recommendation: Disposal must be made according to official regulations.
Safety, health and environmental regulations/legislation specific for the substance or mixtureGHS label elements, including precautionary statementsHazard pictogramsGHS06Signal word DangerHazard statementsH301 Toxic if swallowed.H315 Causes skin irritation.H319 Causes serious eye irritation.H335 May cause respiratory irritation.Precautionary statementsP261 Avoid breathing dust/fume/gas/mist/vapors/spray.P280 Wear protective gloves/protective clothing/eye protection/face protection.P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctorP305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P405 Store locked up.P501 Dispose of contents/container in accordance with local/regional/national/international regulations.National regulationsAll components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.All components of this product are listed on the Canadian Domestic Substances List (DSL).SARA Section 313 (specific toxic chemical listings) Substance is not listed.California Proposition 65Prop 65 - Chemicals known to cause cancer Substance is not listed.Prop 65 - Developmental toxicity Substance is not listed.Prop 65 - Developmental toxicity, female Substance is not listed.Prop 65 - Developmental toxicity, male Substance is not listed.Information about limitation of use: For use only by technically qualified individuals.Other regulations, limitations and prohibitive regulationsSubstance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on themarket and use must be observed.Substance is not listed.Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)GHS06 Skull and crossbonesAcute Tox. 3 H301 Toxic if swallowed.GHS07Skin Irrit. 2 H315 Causes skin irritation.Eye Irrit. 2A H319 Causes serious eye irritation.STOT SE 3 H335 May cause respiratory irritation.Hazards not otherwise classified No data availableGHS label elements, including precautionary statementsHazard pictograms
Reactivity No data availableChemical stability Stable under recommended storage conditions.Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.Possibility of hazardous reactions Reacts with strong oxidizing agentsConditions to avoid No data availableIncompatible materials: Oxidizing agentsHazardous decomposition products:Hydrogen fluorideLithium oxide
Description of first aid measuresGeneral informationImmediately remove any clothing soiled by the product.In case of irregular breathing or respiratory arrest provide artificial respiration.If inhaled:Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.Seek immediate medical advice.In case of skin contact:Immediately wash with soap and water; rinse thoroughly.Seek immediate medical advice.In case of eye contact:Rinse opened eye for several minutes under running water. Consult a physician.If swallowed:Do not induce vomiting; immediately call for medical help.Information for doctorMost important symptoms and effects, both acute and delayed:No data availableIndication of any immediate medical attention and special treatment needed:No data available
ToxicityAquatic toxicity: No data availablePersistence and degradability No data availableBioaccumulative potential No data availableMobility in soil No data availableAdditional ecological information:Do not allow undiluted product or large quantities to reach groundwater, water courses, or sewage systems.Avoid transfer into the environment.Results of PBT and vPvB assessmentPBT: N/AvPvB: N/AOther adverse effects No data available
Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Keep unprotected persons away.Ensure adequate ventilationEnvironmental precautions: Do not allow product to enter drains, sewage systems, or other water courses.Methods and materials for containment and cleanup:Dispose of contaminated material as waste according to section 13.Ensure adequate ventilation.Prevention of secondary hazards: No special measures required.Reference to other sectionsSee Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.See Section 13 for disposal information.