In order to be able to store and transport hazardous materials safely, they are divided into dangerous goods classes in accordance with the ADR Convention. Dangerous goods class 9 accommodates various substances and articles that do not fit into any of the other classes (1 to 8). In this blog post, we have summarized in compact form how Class 9 is defined, what subdivisions apply to it, and what to look out for in terms of legal regulations and labeling.

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In Germany (and also in Europe), the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)is decisive for the transport of substances in dangerous goods class 9. This regulates both the marking (labeling) and the obligations in handling the goods. In addition, there are substance numbers or UN numbers, which are also regulated there. In addition, many other national and international guidelines apply:

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In fact, however, not every substance or object from hazardous substance class 9 is permitted for transport. For example, there are substances that do not meet the requirements according to ADR chapter 3.3 and fall under special provisions 188, 230, 310 or 636. This means that they must not be transported. These substances include, for example:

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This corresponds to the dangerous goods label and indicates the classification. However, depending on the subclass, the warning panel must be supplemented with additional information. For example, there are special “Miscellaneous” labels in Dangerous Goods Class 9, which are an additional designation indicating these properties:

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In addition, the third digit of the packaging code number contains a letter that defines more precisely the substance group for which the packaging design is approved: X indicates suitability for all three packaging groups, Y only for groups II and III, and finally Z only for III.

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All classes of dangerous goods are subject to strict regulations that apply in particular to transport. Therefore, for both storage and transport, several legal regulations must be observed, which should be supplemented by appropriate protective measures.

The substances of dangerous goods class 9 in subclasses M6 to M10 may additionally only be transported in packagings approved by the competent authority. This is due to the environmentally hazardous properties they emit. These substances can be divided into the packing groups that also apply to ADR dangerous goods classes 1 to 8:

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Unlike the other classes, dangerous goods class 9 is primarily considered a containment class. This means that various substances, objects and hazards are grouped together here – namely those that do not fit into any of the other dangerous goods classes. For the most part, these goods are to be defined as dangerous: Often they are genetically modified or emit flammable vapors. Examples of dangerous goods class 9 include the following:

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These special properties also form the basis for a further classification – namely thecategorization of dangerous goods class 9into ADR subclasses. The respective classes are marked with the letter “M” as well as a numbering and serve to describe the emanating hazard in more detail:

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In addition to an appropriate GHS pictogram (think flame for “flammable” or explosion for “explosive”), the following hazardous materials warning label is affixed for Class 9and Class 9A:

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If substances and/or objects of this ADR dangerous goods class are transported in transit, a legally required marking must be affixed. This can be used to indicate that – and, above all, what – danger is posed by this substance.

For the labeling, storage and storage of dangerous goods class 9 substances, protective regulations apply above all for the employer or the workplace. These are anchored in the hazardous substances legislation of the Chemicals Acts and in the Hazardous Substances Ordinance. The legal basis for protective measures for employees can also be found there. Among others, the following aspects are given:

In addition, different goods and materials are assigned to dangerous goods class 9 if they have special predefined properties. According to the official guidelines, these include in particular:

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Dangerous goods class 9 is a special case among the ADR classes - it includes various substances and objects that do not correspond to any other category. Therefore, proper labeling and appropriate precautions must be taken during transportation and handling, which is specified in particular in the ADR specifications.

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Substances, articles and mixtures with potentially hazardous properties must be labeled accordingly according to current legislation. This is the responsibility of the GHS, which provides the classification and labeling obligation with hazard symbols. We have summarized the meaning of the hazard symbols and hazard pictograms, the criteria used to distinguish between them, and the status of supplementary signal words, H and P phrases.

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Both dangerous goods labels and dangerous goods labelsare required, which are available with and without dangerous goods UN numbers. For example, in the event of an accident, arriving rescue and aid forces can immediately assign which measures need to be initiated.

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