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When the Raman spectrum is obtained, it contains information on the vibrational modes of the sample. Each peak in the Raman spectrum corresponds to a particular vibrational mode of the molecule. The wavenumber of the Raman peak is related to the energy of the vibrational mode and the intensity of the peak is related to the magnitude of the change in polarizability associated with the vibration. The Raman spectrum provides a unique fingerprint of the sample, allowing for the identification of different substances and the characterization of molecular vibrations.

Alignment and Tolerance Requirements: Aspheric lenses have strict alignment and tolerance requirements during the manufacturing process, which can result in increased production costs and reduced yields.

Aspheric lensglasses

Photography and Imaging: Aspheric lenses are commonly used in cameras and other imaging devices to improve image quality and reduce optical aberrations. They are used in the manufacture of camera lenses, microscopes, and other imaging systems. Aspheric lenses provide improved resolution and sharpness compared to traditional spherical lenses and are commonly used in high-end camera lenses.

The production of aspheric lenses involves several steps, including the design and prototyping of the lens surface, molding or grinding of the lens surface, and coating of the lens surface to increase its transmission. The design of the aspheric surface is determined by mathematical equations that account for the desired correction of aberrations and the desired image quality. The lens surface can be molded or ground to the desired shape using a variety of techniques, including grinding, diamond turning, and injection molding.

Define aspheric lensvs asphericallens

Aspheric lenses can be made using a variety of materials, including glass, plastic, and other optical materials. Glass aspheric lenses are the most commonly used in high precision optical systems due to their durability and high index of refraction. Plastic aspheric lenses are more flexible, lighter, and less expensive than glass lenses, making them ideal for mass-produced consumer products such as digital cameras, smartphones, and projectors.

Source: JML Optical- https://www.jmloptical.com/blog/spherical-vs-aspheric-lenses-how-theyre-used-in-imaging-applications/

Firebird Optics provides a range of various aspheric lenses with varying materials, focal lengths, diameters as well as optical coatings. If you don’t find what you need feel free to drop us an e-mail at info@firebirdoptics.com.

ScienceEdge Inc. #521 Photonics Center, 2-1 Yamada-Oka, Suita, Osaka 565-0871, Japan Tel：+81-6-6816-2560 Fax : +81-6-6816-2561

Aspheric lenses are an important tool in the field of optics and can be used to correct various types of aberrations, including spherical aberrations. By modifying the shape of the lens surface, aspheric lenses can improve image quality, reduce the size and weight of optical systems, and increase the accuracy and consistency of the focus. With the increasing demand for high-quality imaging in fields such as medicine, photography, and astronomy, the use of aspheric lenses will continue to play an important role in the advancement of optical technology.

Aspheric lenses are optical lenses that deviate from the ideal spherical shape. They are used to correct various types of aberrations, such as spherical aberrations, distortion, and field curvature, which are often present in traditional spherical lenses. The use of aspheric lenses can lead to improved image quality, reduced lens size, and increased system efficiency.

Figure 3. Example of Raman spectra with the horizontal axis converted to wavelengths at 532 nm excitation and 785 nm excitation.

In addition to providing information on the vibrational modes of the sample, Raman spectroscopy can also be used to obtain structural information. The polarization dependence of Raman scattering can be used to determine the orientation of molecules in a sample. By changing the polarization of the excitation laser, it is possible to obtain information on the orientation of functional groups in the molecule.

Figure 2.(c)(d)(e) depict the energy diagram of Rayleigh and Raman scattering processes. The incident light interacts with the molecule and distorts the cloud of electrons to form a “virtual state”. This state is unstable, and the photon is immediately re-radiated as scattered light. Rayleigh scattering is a process in which an electron in the ground state is excited and falls back to the original ground state, involving no energy change. Consequently, Rayleigh scattered light has the same energy as the incident light, meaning both lights have the same wavelength (Figure 2.(c)).

Raman spectroscopy is a vibrational spectroscopy technique that provides valuable information on molecular vibrations and crystal structures with submicron spatial resolution. It is a powerful analytical technique widely used for material identification and evaluation of molecular orientation, crystallinity, and residual stress. Raman spectroscopy can also measure local temperatures, making it useful for the study of thermophysical properties.

Raman spectroscopy is a vibrational spectroscopic technique that provides information on molecular vibrations and crystal structures. This non-destructive method uses a laser light source to irradiate a sample and generate Raman scattered light, which is detected as a Raman spectrum using a spectrometer and a CCD camera.

Asphericlenses vs spherical

Figure 2.(a) Scattering of light by a molecule. (b) Sir Chandrasekhara Venkata Raman. (c)(d)(e) Diagram of the Rayleigh scattering and Raman scattering processes.

Aspheric lenses offer many advantages, such as the correction of spherical aberrations and improved image quality, but also have some disadvantages, including a complex design and manufacturing process, fragility, and limited availability. The choice between using aspheric lenses and spherical lenses will depend on the specific needs of the application and the trade-off between the benefits and limitations of each type of lens.

Freeform Optics: Freeform optics is a production method that is used to produce complex aspheric lenses with low to medium volume production runs. This method involves using advanced computer-controlled machinery to machine the lens material to the desired aspheric shape. The surface quality of the lens produced using this method is typically higher than that produced using other production methods, and it allows for precise control of the lens surface.

Lathe Cutting: Lathe cutting is a production method that is used to produce high-precision aspheric lenses with low volume production runs. This method involves turning a spherical lens blank on a lathe and then cutting the lens material to the desired aspheric shape. The surface quality of the lens produced using this method is limited, and additional surface finishing is typically required to achieve the desired surface accuracy.

Another advantage of aspheric lenses is their ability to reduce chromatic aberrations. Chromatic aberrations occur when different colors of light are focused at different points, causing a rainbow-like effect around the edges of an image. Aspheric lenses can reduce this effect by controlling the refraction of light at different wavelengths, resulting in a more accurate and consistent focus for all colors of light.

In a typical Raman spectroscopic analysis, Rayleigh scattering light is filtered out and only Stokes Raman scattering light is recorded. The Raman spectrum is expressed in a form of intensity of scattered light versus wavenumber (the reciprocal of wavelength, called Raman shift). For example, the Raman peak at 547.14 nm obtained by a 532 nm excitation wavelength can be converted into a wavenumber as below.

The mathematical description of aspheric lenses is based on a surface profile equation that defines the shape of the lens surface. This equation can be represented as a conic section or an aspheric polynomial, and the coefficients or parameters of the equation are adjusted to produce a lens surface that corrects for the desired aberrations. The use of mathematical models and simulations allows for precise control of the lens surface, leading to improved image quality and reduced aberrations.

Fragility: Aspheric lenses are often made from thinner and lighter materials compared to spherical lenses, which can make them more fragile and susceptible to damage.

Astigmatism: Astigmatism is a type of optical aberration that occurs when light from a point source is focused to two separate points, rather than a single point. This can be caused by surface shape imperfections in aspheric lenses.

The production methods for aspheric lenses vary depending on the lens design, the lens material, and the desired production volume.

An additional mathematical representation for the aspheric lens formula. Source: https://escooptics.com/blogs/news/concepts-in-light-and-optics-lenses-part-4-aspheres

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Distortion: Distortion is a type of optical aberration that causes straight lines in the object plane to appear curved in the image plane. This can be caused by surface shape imperfections in aspheric lenses.

Scientific Instruments: Aspheric lenses are commonly used in scientific instruments, such as telescopes and spectrometers, to provide improved image quality and reduced distortion. They are used in the manufacture of astronomical telescopes, microscopes, and other scientific instruments. Aspheric lenses provide improved resolution and accuracy compared to traditional spherical lenses and are an essential component in many scientific instruments.

Diamond Turning: Diamond turning is a production method that is used to produce high-precision aspheric lenses with low to medium volume production runs. This method involves using a diamond-tipped cutting tool to machine the lens material to the desired aspheric shape. Diamond turning allows for precise control of the lens surface, and the surface quality of the lens produced using this method is typically higher than that produced using other production methods.

Aspheric lenses can be affected by various surface shape imperfections, including spherical aberration, astigmatism, coma, distortion, surface roughness, and waviness. The degree and type of surface shape imperfections will depend on the lens design, the manufacturing process, and the lens material properties. Precise control of the surface shape is critical for achieving the desired performance in aspheric lenses.

Surface Roughness: Surface roughness is a deviation from a smooth surface that can cause light scattering and reduced image quality.

where z is the height of the surface above the optical axis, r is the radial distance from the optical axis, R is the radius of curvature of the surface, C is the conic constant, k is the conic coefficient, and A, B, and C are the polynomial coefficients. The polynomial coefficients can be adjusted to correct for specific aberrations.

The mathematical description of aspheric lenses is based on a mathematical model called a surface profile equation, which defines the shape of the lens surface.

The characteristic fingerprint pattern in a Raman spectrum enables the identification of substances, including polymorphs, and the evaluation of local crystallinity, molecular orientation, and residual stress (tensile or compressive).

Aspheric lenses are widely used in a variety of applications across various fields, including photography and imaging, laser systems, medical devices, scientific instruments, and display technology. Aspheric lenses provide improved resolution, accuracy, and image quality compared to traditional spherical lenses, making them an essential component in many precision optical systems.

Medical Devices: Aspheric lenses are commonly used in medical devices, such as endoscopes, to provide improved image quality and reduced distortion. They are also used in ophthalmic lenses, such as contact lenses and intraocular lenses, to correct visual aberrations and improve visual acuity.

When light interacts with matter, almost all of the scattering is an elastic process (Rayleigh scattering) with no energy change. However, a very small percentage of scattering is an inelastic process, leading to scattered light with different energy from the incident light (Figure 2.(a)). This inelastic scattering of light was predicted theoretically by Adolf Smekal in 1923 and first observed experimentally by Chandrasekhara Venkata Raman (Figure 2.(b)) in 1928, and it is called Raman scattering (Raman effect).

In the Raman spectra of materials with internal stress or strain, it is known that the position of the Raman peak is shifted relative to the position of the material without stress. By evaluating this peak shift, it is possible to determine whether the stress is compressive or tensile and the magnitude of the stress.

Reduced Size and Weight of Optical Systems: Aspheric lenses can reduce the size and weight of optical systems as they can correct for multiple aberrations with a single lens.

The use of aspheric lenses can result in improved image quality, with sharper and clearer images and increased resolution. Aspheric lenses can also reduce the size and weight of optical systems, as they can correct for multiple aberrations with a single lens. This is because aspheric lenses can reduce spherical aberrations, distortion, and field curvature, which are often present in traditional spherical lenses.

Aspheric lenses solve this problem by modifying the shape of the lens surface. Instead of a spherical surface, aspheric lenses have a surface that deviates from a perfect sphere. This allows for a more precise control of the refractive index, resulting in a more accurate focus of light. The aspheric surface is designed using mathematical equations that account for the desired correction of aberrations and the desired image quality.

In terms of Raman thermometry, the local temperature of the sample under the focused laser spot can be easily determined by fitting the spectral position and line width of the observed Raman mode. The temperature increase causes thermal expansion of a sample, resulting in a redshift of the Raman peak’s position and broadening of the linewidth of the Raman peak.

Raman spectroscopy can also be used to study the crystallinity of a sample. The Raman spectrum of a crystal will exhibit sharp peaks due to the vibrational modes of the crystal lattice. By analyzing the peak widths and intensities, it is possible to obtain information on the crystallinity and orientation of the crystal.

Increased Accuracy and Consistency of Focus: Aspheric lenses can increase the accuracy and consistency of the focus for all colors of light, resulting in a more accurate and consistent image.

Light is often expressed in terms of wavelength, but in Raman spectroscopy, it is common to use wavenumbers that are linearly related to energy and to represent the Raman spectrum in a form that is independent of the excitation wavelength. For example, the Raman peak of crystalline silicon always appears at a wavenumber of 520.3 cm-1 at room temperature, no matter what excitation wavelength is used. However, if wavelength is used as the unit of abscissa, the Raman peak of silicon appears at 547.14 nm for 532 nm excitation and at 818.43 nm for 785 nm excitation.

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The Rayleigh scattering process is dominant, and Raman scattering is an extremely weak process, with only one in every 106 - 108 photons scattered. The ratio of Stokes Raman and anti-Stokes Raman scattering depends on the population of the various states of the molecule. At room temperature, the number of molecules in an excited vibrational state is smaller than that in the ground state. Therefore, generally, the intensity of Stokes Raman light is higher than that of anti-Stokes Raman light. As the temperature of the sample increases, the intensity of the anti-Stokes Raman light increases relative to the Stokes scattering light. Thus the local temperature of the sample can be measured from the intensity ratio of the two lights.

The surface profile equation can be expressed as a polynomial or a more complex mathematical function. The coefficients of the polynomial or the parameters of the mathematical function are chosen to produce a lens surface that corrects for the desired aberrations.

Reduced Chromatic Aberrations: Aspheric lenses can reduce chromatic aberrations, which occur when different colors of light are focused at different points, causing a rainbow-like effect around the edges of an image.

where x, y, and z are the coordinates of a point on the lens surface and A, B, C, D, E, and F are the coefficients that determine the shape of the surface. By adjusting the values of the coefficients, the lens surface can be designed to correct for specific aberrations.

Asphericlenses advantages disadvantages

These advantages make Raman spectroscopy crucial in research and development (R&D) and quality assurance/quality control (QA/QC) in several industries and academic fields such as semiconductors, polymers, pharmaceuticals, batteries, life sciences, and more.

Aspheric lenses are precision optical components, and as such, they can be affected by various surface shape imperfections that can degrade their performance. Some of the main surface shape imperfections of aspheric lenses include:

Display Technology: Aspheric lenses are commonly used in display technology, such as projectors and head-mounted displays, to provide improved image quality and reduced distortion. They are used in the manufacture of projectors, virtual reality and augmented reality displays, and other display-based applications. Aspheric lenses provide improved resolution and image quality compared to traditional spherical lenses and are an essential component in many display-based applications.

Coma: Coma is a type of optical aberration that causes light from a point source to be focused to a comet-like shape, rather than a point. This can be caused by surface shape imperfections in aspheric lenses.

Spherical Aberration: Spherical aberration is a type of optical aberration that occurs when light from a point source is not focused to a single point. In aspheric lenses, this can be caused by deviations from the desired surface shape or by variations in the lens material properties.

Spherical aberrations occur because of the difference in the refractive index between the center and the edge of a spherical lens. Light passing through the center of the lens is focused to a single point, but light passing through the edge is not focused correctly, leading to a blurred image. This effect is more pronounced for lenses with a large aperture, such as camera lenses or telescopes.

The spherical shape of traditional lenses is determined by the radius of curvature of the lens surface. In order for light to be focused correctly, the surface must be a perfect sphere. However, this shape can cause aberrations that limit the resolution and contrast of the image. Aspheric lenses are designed to overcome these limitations by modifying the shape of the lens surface to correct for aberrations.

Improved Image Quality: The use of aspheric lenses can result in improved image quality, with sharper and clearer images and increased resolution.

Correction of Spherical Aberrations: Aspheric lenses are designed to reduce spherical aberrations, which cause blurred or distorted images, by modifying the shape of the lens surface. This results in sharper and clearer images with increased resolution.

Aspheric lenses are precision optical components that have a wide range of applications across various fields. Some of the main application examples of aspheric lenses are described below.

In conclusion, the production methods for aspheric lenses vary depending on the lens design, the lens material, and the desired production volume. Methods such as spherical molding, lathe cutting, diamond turning, molding and replication, and freeform optics are used to produce aspheric lenses with varying levels of precision and surface quality. The choice of production method will depend on the desired production volume, the lens design, and the desired surface accuracy and quality.

Aspheric lensbenefits

Laser Systems: Aspheric lenses are commonly used in laser systems to collimate laser beams and focus the laser light to a small spot. They are used in the manufacture of laser pointers, laser cutting machines, and other laser-based applications. Aspheric lenses provide improved beam quality and beam stability compared to traditional spherical lenses, making them an essential component in many laser systems.

Complex Design and Manufacturing Process: Aspheric lenses require a more complex design and manufacturing process compared to spherical lenses, which can lead to higher costs.

Limited Availability: Aspheric lenses may not be available in certain sizes or configurations, which can limit their use in certain applications.

In contrast, Raman scattering can be classified as Stokes Raman scattering and anti-Stokes Raman scattering. Stokes Raman scattering is a process in which an electron is excited from the ground state and falls to a vibrational state, involving energy absorption by the molecule (Figure 2.(d)). Thus, Stokes Raman scattered light has less energy (longer wavelength) than incident light. On the other hand, anti-Stokes Raman scattering is a process in which an electron is excited from the vibrational state to the ground state, involving an energy transfer to the scattered photon (Figure 2.(e)). Consequently, anti-Stokes Raman scattered light has more energy (shorter wavelength) than incident light.

Molding and Replication: Molding and replication is a production method that is used to produce aspheric lenses with high volume production runs. This method involves creating a mold of the desired aspheric shape and then using this mold to replicate the lens using a suitable lens material. The surface quality of the lens produced using this method depends on the quality of the mold, and additional surface finishing may be required to achieve the desired surface accuracy.

Spherical Molding: Spherical molding is a production method that is used to produce simple aspheric lenses with low volume production runs. This method involves pressing a heated lens material into a spherical mold, which then deforms the lens material into the desired aspheric shape. The surface quality of the lens produced using this method is limited, and additional surface finishing is typically required to achieve the desired surface accuracy.

Raman thermometry is a contactless, steady state technique for measuring thermal conductivity based on probing of the local temperature using the Raman signal as a thermometer.