Chemical polarizationexamples

Chemically induced polarization of the nuclei (CPN) was detected in the products of the reactions of organic phosphites with hydroperoxides.

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Pershin, A.D., Pobedimskii, D.G., Kurbatov, V.A. et al. Chemical polarization of nuclei. Russ Chem Bull 24, 506–510 (1975). https://doi.org/10.1007/BF00927465

The authors are grateful to the designer of the NMR radiospectrometer, é. A. Laud, for the preparation, tuning, and ensuring of the reliability of operation of the spectrometer.

What ispolarizationin chemistry Class 11

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é. G. Chebotareva, D. G. Pobedimskii, N. S. Kolyubakina, N. A. Mukmeneva, and P. A. Kirpichnikov, Kinetika i Kataliz,14, 891 (1973).

D. G. Pobedimskii and P. A. Kirpichnikov, Summaries of Reports at the Fifth All-Union Conference on Organophosphorus Compounds [in Russian], Nauka (1972).

The results of CPN of31P are evidence of the occurrence of reactions of phosphites with hydroperoxides according to two pathways: radical (side) and nonradical (basic). Polarization of the nuclei arises in the products of radical conversion.

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