Circularly polarizedlight

A reflection of light is caused by a wave front inducing an oscillation in a charged particle which then causes a new wavefront to form. In a reflective surface, the valence electrons are the charged particles that absorb those incident wavefronts. Atomic electrons have more freedom to move parallel to the material’s surface, especially if they are electrons in the conductive band of a metal like silver.

I have learnt about Brewster's angle, and how at a particular angle all light reflected is polarised, but do not understand why. Is this something that could be explained to a guy that doesn't have a Ph.D in physics?

Plane polarizedlight

Consider medium particle at P moving Up down Up down (out of plane of screen) It emits light in all directions, except at U D. So, Reflected light has component along plane of light.

But using Huygens principle, you see light can actually move in two ways. It can either reflect back at $\theta$ angle or refract to medium.

So there it is - for this very special orientation, the reflected light must be fully polarized. If you do the math carefully (see Fresnel's equations), you will see that you will have some polarization at any angle - again, because the amount of polarization in the reflected light depends on the ability of the dipoles in the material to excite a reflected wave. The Brewster angle is a special case that gives “pure” polarization; at other angles, there will be partial polarization. Incidentally this is why polarized sunglasses help reduce “glare” - if the majority of surfaces you look at are near-horizontal (for example, a body of water), then the polarization of the reflected light will be mostly horizontal; and since polarizing sunglasses only allow vertically polarized light through, reflections are reduced.

Polarized and unpolarizedlight

So, waves vibrating parallel with the surface of the material can induce continuous movement in the electrons of the material’s surface while waves perpendicular is limited to electron shell configurations.

What is plane polarizedlightin Chemistry

The reflection is actually caused by the motion of electrons in the medium. Now you can see that the electrons, which move along the direction of the E vector, are moving parallel to the direction of the reflected beam. An electrical dipole that is oscillating can send a wave in all directions - except the direction it is pointing (if you think about it, looking at the dipole "end-on" you don't see it moving: if it doesn't seem to be moving, it shouldn't be seen to be radiating towards you...). This entire analysis is only for the E field with the polarization drawn: if the incident light contains a component of E field perpendicular to the sketch (in and out of the page), that component will be able to radiate along the reflected direction from inside the dielectric.

If you have an incident ray that is polarized with the E field up and down (in the plane containing the incident ray and the normal to the surface), then when that ray is refracted, it contains a component of electric field that is perpendicular to the refracted ray (and still in the same plane).

You can imagine when particle vibrate along LR , it emits light in all directions except along LR. So, there is no component of light along LR. So, in reflected light no LR component is present.

For the electron to move perpendicular to the surface of the material, the electron would have to move towards and away from the atomic nucleus. This movement is restricted to particular quanta determined by the electron orbitals the electron can transition into and out of.

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